Platinum Complexes of Aromatic Selenolates
نویسندگان
چکیده
منابع مشابه
synthesis of binuclear platinum complexes containing biphosphine ligand
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Self-assembled monolayers of aromatic selenolates on noble metal substrates.
Self-assembled monolayers (SAMs) formed from bis(biphenyl-4-yl) diselenide (BBPDSe) on Au(111) and Ag(111) substrates have been characterized by high-resolution X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, infrared reflection absorption spectroscopy, water contact angle measurements, and scanning tunneling microscopy (STM). BBPDSe was found to form c...
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In an approach to design drugs with higher affinity for π-π stacking and electrostatic interactions with targeted biomolecules, complexes of the type [{cis-Pt(A)2 (L)}2 -μ-{trans-1,4-dach}](NO3 )4 ((A)2 =(NH3 )2 or ethylenediamine (en), L=quinoline (quin) or benzothiazole (bztz), dach=trans-1,4-diaminocyclohexane) were synthesized. The quinoline complex, [{cis-Pt(en)(quin)}2 -μ-(dach)](NO3 )4 (...
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trans-Bis(alkynyl)palladium complexes, trans-[(PEt3)2Pd(-CtCC{dO}NR2)2] (NR2 = NMe2 (2a), N(CH2)4 (2b)), were synthesized by two different methods: (a) by copper-catalyzed reaction of HCtCC(dO)NR2with [PdCl2(PEt3)2] under basic conditions and (b) by treatingHCtCC(dO)NR2 with AgNO3 followed by transmetalation of the alkynyl ligand from silver to [PdCl2(PEt3)2]. The reaction of AgCtCC(dO)NMe2 (3a...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2010
ISSN: 1434-1948
DOI: 10.1002/ejic.201000357